Can someone point me to a decent configuration guide for our

We use Windows XP with Client 32 4.90sp2 and want to make sure we are
doing it the best way we can.

We do not have ZEN so each PC must be set up manually.

We do not have Windows Networking Client installed nor do we have any
Windows domains/servers.

We do have NW6.5sp5 servers - one with DHCP running and another that
is our BorderManager firewall/proxy/VPN.

I'm specifically looking for best ways to set the users. For example,
when we set up a network account: jsmith, we then set up an account
named jsmith on the Windows workstation so that jsmith can login to
both the WS and the network at the same time.

This is the best way to do this, correct?