I'd like to create a brand new Group Policy for my workstations, but I do not know where to begin. I current use DLU for my users to access the machines, but I'd like to use Group Policy Settings to configure the workstations.

Also, is it possible to specify the default printer on a computer when a user logs in (possibly using Group Policies).

Also, when if comes time to roll out the policy, do I associate the policy with the User or the Workstation?